Renewable resources are gaining special attention as substitutes for petroleum based products. Thus biobased polymers obtained from vegetable oils present a good, green alternative to fossil based polymers in terms of biodegradability and toxicity, thereby allowing their application for high value added and/or biomedical purposes.
In this study, Acyclic Diene Metathesis (ADMET) and thiol-ene miniemulsion polymerization method was followed to synthesize high molecular weight polymers. In addition to the chemical reactions leading to synthesis of high molecular weight polymers, miniemulsion polymerization method enabled the production of polymeric nanoparticles with unique characteristics and vast commercial interest.
Characteristic studies revealed that the synthesized nanoparticles did not present any cytotoxic effect on murine fibroblast (L929) and human cervical cancer (HeLa) cells and showed high blood biocompatibility.
Biopolyamides market is estimated to grow well in the coming years till 2025. Undecanoic acid and sebacic acid derived from castor oil are among the most dominant raw materials used in the production of bio based polyamide. Owing to the eco logical benefits, bio based polyamides are gaining acceptance and are anticipated to be the fastest growing product segment during the coming years.
Automotives is the largest application segment for polyamide and the trend is expected to continue in the near future. Demand for polyamide in packaging applications is expected to outdo other application segments in terms of growth rate during the coming years.
Scientists from Columbia performed an experiment to develop a kinetic model for high CO2 pressure carbonation of epoxidized castor oil which can be used for production of thermoset polymers and non-isocyanate polyurethanes.
Results showed that because of the polyfunctional character of the product, it could find applications as a monomer and as a synthetic building block for other bio-based chemicals.
Researchers from India prepared castor oil polyurethane from pre-polymer oftoluene diisocyanate (TDI) and castor oil with dibutyl tin dilaurate (DBTDL) catalyst. Water was used as blowing agent. The rate of forming was increased by increasing catalyst and water content. On other hand the cell size of the PU decreased with increasing amount of the catalyst and water content.
Characterization studies were performed to analyse the properties of synthesized foam.
Scientists from China synthesized hybrid polyurethanes with double-decker silsesquioxane (DDSQ) using castor oil and isophorone diisocyanate (IPDI) as feedstock. Double-decker octaphenyl silsesquioxanetetraol (DDSQ) was prepared and characterized by spectroscopy.
Results showed that with the inclusion of DDSQ, the hydrophobicity of the hybrid material was significantly improved.
EAI, the parent company of CastorOil.in, had been studying the bioplastics industry for the past few years and in the recent past we had the opportunity to look at the sector, in India and worldwide at close quarters.
Based on these, we have put together an exclusive team to provide strategic and market consulting for the global bioplastics industry.
Cellulose fibre reinforced composites are considered suitable alternative to plastic products due to the environmental problems caused by the latter. However, pure cellulose fibres have a high hydrophilicity. Moreover, the polar character of these fibres causes their low compatibility with partially or totally hydrophobic polymer matrices.
Owing to the poor wettability and adsorbability towards polymers, the surface modification of the fibres surface is essential, in order to improve the fiber/polymer compatibility and their interfacial adhesion. Hence researchers from France conducted a study to improve the properties of cellulose fibres by modifying the cellulose fibres with trialkoxysilane from castor oil.
Characteristic studies were carried out for the modified cellulose-castor oil polyurethane composites. Results showed that compared with the crude cellulose fibres, the organosilane treatment reduced the hydrophilicity of the natural fibres and increased the fiber/matrix compatibility.
Scientists from India performed an experiment where asphalt which is commonly used for road pavement was modified using castor oil based polyurethane to improve the properties of asphalt such as resistance to permanent deformation and to reduce the fatigue.
Polyurethane pre-polymer (PUP) was prepared by using castor oil and toluene diisocyanate (TDI). Asphalt modification was done using castor oil (C.O.) and PUP. Results showed that polymer modified asphalt showed improvement in properties such as hardness and softening point thereby making the pavement application smooth.