Electroactive Polyurethane/Siloxane Derived From Castor Oil as a Versatile Cardiac Patch

Scientists from Italy conducted an experiment to synthesize electroactive polyurethane/siloxane films from castor oil for use as a cardiac patch. The electroactive films containing aniline tetramer were prepared through sol gel reaction of trimetcastor oil polyurethanehoxysilane functional intermediate polyurethane prepolymers obtained from castor oil and polyethylene glycol.

Physicochemical, mechanical and electrical conductivity of samples were evaluated and correlated with their structural characteristics. Results showed that the prepared films were compatible with proliferation of C2C12 and had the potential to enhance myotube formation even without electrical stimulation.

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Synthesis and Characterization of Castor Oil-based Polyurethane for Potential Application as Host in Polymer Electrolytes

Researchers from Malaysia conducted an experiment to synthesize castor oil based polyurethane and analyse its potential application as a base material in polymer castor oil polyurethaneelectrolytes. Castor oil polyols were synthesized and mixed with 4,4′-diphenylmethane diisocyanate to synthesize the desired biobased polyurethane.

Characteristic studies showed that the synthesized polyurethane had favourable properties and hence could be used as a base material in polymer electrolytes.

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Effect of Castor Oil as an Auxiliary Stabilizer in the Production of Flexible Polyurethane Foams

Researchers from Nigeria performed an experiment to castor oil polyurethaneanalyze the effect of castor oil as an auxiliary stabilizer in the production of polyurethane foams.  Castor oil was used as a substitute to silicone oil at different percentages.

The results showed that castor oil could be a best partial substitute for silicone oil at higher densities.

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Influence of NCO/OH and Transesterified Castor Oil on the Structure and Properties of Polyurethane: Synthesis and Characterization

Scientists conducted an experiment to analyze the influence of isocyanate, hydroxyl groups and transesterified castor oil on the structure and properties of polyurethane. castor oil polyurethane Polyurethane was synthesized using transesterified castor oil and partially Biobased isocyanate with varying concentrations of isocyanate and hydroxyl groups.

The chemical and mechanical properties, thermal stability of polyurethanes were analyzed. Results showed that NCO/OH molar ratio had profound effect on the tensile properties and modulus of polyurethanes.

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Development of Green Waterborne UV Curable Castor Oil Based Urethane Acrylate Coatings: Preparation and Property Analysis

castor-oil-800067Scientists from India conducted an experiment to analyze the suitable source needed to manufacture UV-curable polyurethane dispersions for coating applications. They synthesized a series of novel waterborne UV-curable polyurethane dispersions from castor oil, Isophorone diisocyanate (IPDI), Dimethylolpropionic Acid (DMPA)and Hydroxyethylmethacrylate (HEMA) by acetone process.

The prepared UV-PUDs were mixed with three different monomers and characterization studies were conducted. Results showed that the combination of renewable resource (castor oil) and environment compliant technology could make these UV-PUDs suitable for coating applications.

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Thermo-mechanical Analysis of Foam Based on Castor Oil Polyol

Researchers from India conducted an experiment to analyze the thermo-mechanical properties of castor oil based polyol foam. Castor oil was extracted usicastor oil polyurethaneng hydraulic press and was allowed to react with toluene diisocyanate and other material to obtain the polyurethane foam. Incorporation of castor oil increased the hardness, density and compression of the foam. The cost of production also significantly decreased.

These results suggest that castor oil could be widely used for the manufacture of polyurethane foam.

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Characterization of Novel Castor Oil-Based Polyurethane Polymer Electrolytes

Researchers from Malaysia conducted an experiment to analyCastor oil polyurethaneze the application of castor oil based polyurethane as a host in polymer electrolyte for electrochemical devices. The synthesized castor oil polyurethane was added with lithium iodide and sodium iodide in different wt% to form a film of polymer electrolytes.

The results showed that castor oil based polyurethane polymer electrolytes can be used  as an alternative membrane for electrochemical devices.

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Preparation and Properties of Waterborne Bio-based Polyurethane/Siloxane Cross-Linked Films by an in situ Sol–gel Process

Scientists from China prepared waterborne castor oil -based polyurethane –sCastor oililica hybrid materials with chemically bonded polymer matrix and silica nanoparticles.  The formation of the cross-linking structures in the polyurethane system was confirmed by FTIR.

The results showed that the nano-silica in the polyurethane matrix improved both hydrophobicity and thermal stability of the resulting hybrid polyurethane films. Thus this process can help in the design of bio-based hydrophobic waterborne polyurethane films with favourable thermal stability and optical transmittance.

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Effect of Modified Silica Nanoparticle on the Properties of Bio-Based Polyurethane

nanocompositesResearchers developed bio-based polyurethane (BPU) using a castor oil/poly (ε-caprolactone) hybrid polyols and hydrophobic BPU ultrafine fibres containing modified silica (m-silica) by electrospinning process. The rheological analysis of the network structure between the BPU and m-silica showed improved mechanical properties and thermal stability. The average fibre diameter of the hybrid ultrafine fibres decreased with increasing m-silica content. Moreover, the m-silica nanoparticle provided an effective surface wettability to BPU ultrafine fibres, thus making it a hydrophobic molecule. All these improved properties makes BPU/m-silica ultrafine fibres, a better replacement for petroleum-based polyurethane membrane, thus allowing its application in the field of bio filters, eco-friendly textiles, and biomedical engineering.

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Study of the Mechanical, Thermal Properties and Flame Retardancy of Rigid Polyurethane Foams Prepared from Modified Castor-Oil-Based Polyols

A team of researchers from China conducted study on mechanical, thermal properties and flame retardancy of rigid polyurethane foams (PUF) prepared from modified castor oil (MCOHomepagecarroussel-research1) based polyols. The polyurethane foam was prepared in two stages. The first stage is the conversion of castor oil into glycerides by alcoholysis with glycerol and pentaerythritol. Next stage is the synthesis of polyester polyols by condensation alcoholysis of castor oil and phthalic anhydride. Results from various analyses showed that components of the MCOs and commercial polyester polyol PS-3152 are similar in their foaming behaviour. Results from analyses like mechanical testing, flame retardancy testing, thermogravimetric analysis and cone calorimetry showed that PUF from modified Castor oil based polyols had a better mechanical properties and thermal conductivities than PS-3152 based Polyurethanes. High thermal stability is exhibited by MCO based PUFs, during pyrolysis.

It is also found that addition of ammonium pyrophosphate decreased their heat release rate, total heat release and mass loss, thereby having synergistic effect with phthalic anhydride polyester polyols. All of these unique properties of MCO-modified rigid PUFs were correlated to the structures of these PUFs.

These findings may lead to the development of a new type of polyurethane foam using castor oil.

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