Development of Oleogels Using Castor Oil Derivatives for Lubricating Greases

This blog post is an abstract of the research work focused on the development of new oleogels, using castor oil and cellulose derivatives, which could be potentially used as biodegradable lubricating greases

Thermal and thermo-rheological behaviours of castor oil and cellulose derivatives were characterised by means of TGA analysis and SAOS measurements, in order to evaluate the evolution of oleogel microstructure with temperature. Moreover, both roll-stability and leakage tendency standard tests, usually performed in the grease industry, were used to evaluate the mechanical resistance of each sample. The evolution of biogrease linear viscoelasticity functions with frequency is quite similar to that found for traditional lithium lubricating greases. However, the influence of temperature on biogreases linear viscoelasticity functions is less important than that found for traditional greases. In general, the biogrease samples studied show both slightly lower mechanical stability and higher leakage tendency than traditional lubricating greases. The use of a blend of ethyl and methyl cellulose as thickener provides a mechanical stability comparable to that found for commercial greases.

Read:http://pubs.rsc.org/en/Content/ArticleLanding/2009/GC/b820547g#!divAbstract

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Extraction and Characterization of Drilling Fluid from Castor Oil

Research Article – Drilling fluid is an essential component in drilling operations. It is used to prevent blowouts by creating adequate hydrostatic pressure, lubricating the walls of a well and the drill string, flushing to the surface of cuttings, and keeping the drill bit clean and cool. Extraction, characterization and formation of drilling fluid from castor seed oil were investigated. The castor seeds used were obtained from a local market and the extraction of the oil was done mechanically. The extracted oil characteristics such as specific gravity, pH, acid value, iodine value, saponification value, refractive index and viscosity were within the standard range before before formulating it to drilling fluid by the addition of additives. The result of the formulation obtained showed that the formulated drilling fluid had an electrical stability of 222 V, High Pressure/High Temperature of 8.8, mass funnel viscosity at 30 and 50 oC were 26.5 and 25 s, respectively; chemical alkalinity was 0.3 and excess lime of 0.39 Ib/bbI. The findings in this research have shown that formulated drilling fluid from castor seed oil is safe as drilling fluid and has characteristics close to that of the standard drilling mud equivalent circulating density 99. The formulated drilling fluid can adequately serve as an alternative to the commercial products.

Read:http://www.issr-journals.org/ijias/abstract.php?article=IJIAS-13-091-02

US Castor Crop Concerns and Solutions

Hello Readers,

This post contains some excerpts from an article on US castor crop research published by the South West Farm Press Editorial, US .

We thought to share with you since we found it interesting. Hope you like it.

There is little or no commercial castor production in the U.S.  Castor production in US comes with a reputation, largely related to the fear of growing a potentially toxic crop. Ricin, a protein toxin found only in the endosperm of castor seed, can represent up to 5 percent of the meal weight remaining after oil extraction.

Researchers say the long term solution for castor crop development in US is to develop castor varieties that greatly reduce toxicity. Some of the ongoing research efforts in US include:

A group of Texas A&M and Texas Tech researchers have been working together on a castor variety that greatly reduces risk and still offers value in production. Working with the best tools agricultural science can offer, they have aggressively developed a semi-dwarf castor variety with reduced ricin levels and one that allows for mechanized production.

A new variety known as the Brigham, so named after the advancement of castor research by Dr. R.D. Brigham of the USDA Research Center in Lubbock, has provided promising results, effectively reducing ricin toxicity by 70 to 90 percent. A semi-dwarf variety, Brigham also allows for mechanized commercial production.

Read more to know more about the castor research efforts in US : http://southwestfarmpress.com/management/bio-science-addresses-concerns-over-castor-crop?page=1

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Some Useful Castor Research Articles

Hello readers,

This blog post provides you with linteresting articles that would be useful for the castor oil researchers

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BASF Now Offers Bio-based Nylon for Textiles

German chemical giant BASF has said it will now offer its bio-based nylon, which is derived from castor oil, in a version suitable for monofilament applications that can be used for textile fibres. Castor oil based sebacic acid is used to produce the company’s Ultramid® S Balance.

The high performance polyamide 6.10, partly based on renewable resources, is available in various viscosities. In compounded and glass-fiber reinforced versions, BASF has already introduced the material in different commercial applications, e.g. in a design lamp or automotive quick connectors.

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Castor Oil in Artificial Tear Reduces Evaporation; Helps Dry Eye Sufferers

Researchers from the Optometric Technology Group in London have found that an eye drop containing castor oil and demulcents was associated with a reduction in tear film evaporation rate and increase in ocular comfort.

The castor oil was detected in the basal tear after 30 days of use and at least 3 hours after the last eye drop instillation.Researchers conducted a prospective bilateral evaluation of evaporative dry eye sufferers using Refresh Optive Advanced (Allergan) for 1 month. Results showed that a detectable amount of castor oil in the tear samples was associated with a lower evaporation rate at 30% [low] relative humidity.

Read more: http://www.healio.com/optometry/cornea-external-disease/news/print/primary-care-optometry-news/%7B46c51a6a-bfc0-48e5-9c90-09a88e3070d8%7D/study-shows-castor-oil-in-artificial-tear-decreases-evaporation-increases-comfort

CastorOil Based Plastics Used in the LED Lamps Design

Wastberg , a Swedish lighting company, that manufactures economic and energy efficient lighting solutions, has designed a lamp that uses a plastic made with castor bean oil.  Called the Winkel w127, the lamp uses LED lights that are designed to shine for 50,000 hours.

Winkel w127 is manufactured of solid fiberglas reinforced biopolyamide, which is made out of castor oil.

Source: http://www.treehugger.com/interior-design/swedish-design-makes-castor-oil-cool.html

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Pumpsets Can Now Use Castor Oil As A Fuel

Sheik Mastan Vali, a Indian mechanic by profession, who has been crusading the use of castor oil to run motor cars and protect the environment from pollution, has designed a novel agricultural pumpset, which could be operated using castor oil.

He claims that one litre diesel would help the farmer to operate the pumping machine for one hour, but the castor oil would help him operate the machine for three to four hours because of the presence of natural lubricants in castor oil.

A prototype pump engine which uses the castor oil can lift water from wells with the depth of 70 meters.

Read more from: http://www.thehindu.com/todays-paper/tp-national/tp-andhrapradesh/pumpset-that-runs-on-castor-oil-designed/article4285130.ece

India – Castor Seed October,November Futures Gain

On the National Commodity and Derivatives Exchange, October contracts increased by Rs 35 to Rs 3,474 a quintal with an open interest of 1,25,890 lots.

November contracts gained by Rs 41 at Rs 3,579, with an open interest of 44,910 lots.

On the Rajkot Commodity Exchange, December contracts increased by Rs 44 to Rs 3,714. RCX spot castor declined by Rs 37.50 to Rs 3,410 a quintal.

Castor oil traded flat at Rs 720 for 10 kg.

Spot prices, however, decreased as recent rains have raised hopes of higher sowing of the crop that is grown during the rabi season.

Read More:http://www.thehindubusinessline.com/markets/commodities/castorseed-futures-gain-on-value-buying/article5168034.ece

Safety Assessment Report of the Products from Castor Oil

This post presents a few excerpts from the final report on the safety assessment of castor seed oil and its derivatives.

  1. Castor oil is classified by Food and Drug Administration (FDA) as generally recognized as safe and effective for use as a stimulant laxative
  2. Although chemically similar to prostaglandin E(1), Ricinoleic Acid did not have the same physiological properties. These ingredients are not acute toxicants, and a National Toxicology Program (NTP) subchronic oral toxicity study using castor oil at concentrations up to 10% in the diet of rats was not toxic. Other subchronic studies of castor oil produced similar findings
  3. Neither castor oil nor Sodium Ricinoleate was genotoxic in bacterial or mammalian test systems. Ricinoleic Acid produced no neoplasms or hyperplasia in one mouse study and was not a tumor promoter in another mouse study, but did produce epidermal hyperplasia.
  4. Clinically, castor oil has been used to stimulate labor. Castor oil is not a significant skin irritant, sensitizer, or photosensitizer in human clinical tests, but patients with occupational dermatoses may have a positive reaction to castor oil or Ricinoleic Acid

Read the report here – http://www.ncbi.nlm.nih.gov/pubmed/18080873

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